Emeishan Large Igneous Province Research Articles

Multistage dolomitization influenced by the Emeishan large igneous province: Petrographical and geochemical evidence

The formation of large igneous provinces (LIPs) seems to require a series of conditions conducive to massive dolomitization; however, the specific mechanisms remain unclear. Based on petrographic, geochemical and fluid-inclusion microthermometry analyses, this study identifies the types of dolomites in the Maokou Formation (Middle Permian) in the eastern Sichuan Basin. It analyses the related dolomitization fluids and discusses the influencing mechanisms of the Emeishan large igneous provinces (ELIP) on dolomitization at different stages. Three types of dolomite were identified: (1) fabric-retentive, very finely crystalline, planar-s to nonplanar-a dolomite (MD1); (2) fabric-retentive, fine to medium crystalline, planar-s to nonplanar-a dolomite (MD2); and (3) medium to coarsely crystalline, nonplanar (saddle) dolomite (SD). MD1 exhibited dark-red luminescence under cathodoluminescence and rare earth element patterns that are similar to those of lime mudstone, indicating that its dolomitization fluid was medium-salinity Permian seawater. MD2 displayed orange-red luminescence under cathodoluminescence, with a high Ba content (mean: 397.5 ppm) and positive Eu anomalies (mean: 2.34), indicating that its dolomitization fluid was a mixture of shallowly buried seawater and a small amount of external hydrothermal fluid. SD showed red luminescence under cathodoluminescence, with the highest Ba content (mean: 9820.4 ppm) and significant positive Eu anomalies (mean: 3.165), indicating that its dolomitization fluid was mainly ELIP-related hydrothermal fluid with a small amount of residual seawater. Before the ELIP activity, no dolomite occurred in the study area. In the initial stage of ELIP activity, upwelling of the Emeishan mantle plume led to a shift in sedimentary patterns, promoting the occurrence of reflux dolomitization and the formation of MD1. In the intermediate stage of ELIP activity, the activation of basement faults promoted the occurrence of thermal convection dolomitization, resulting in MD2 formation. In the peak stage of ELIP activity, large-scale eruption of Emeishan basalt led to the development of hydrothermal dolomitization, forming SD. This study provides an approach to the investigation of the influences of LIPs on dolomitization processes.

Two pulsed activities of the Emeishan large igneous province in southwestern China inferred from dolomite U-Pb geochronology and significance

The Emeishan large igneous province (ELIP) was a major geological event that took place around the Middle−Late Permian boundary. The major episode of the ELIP is generally considered to have occurred at 260−259 Ma, although an increasing number of geological data have suggested that multiple episodes of magmatic activity might have occurred. Here we report a study of a Lower Permian dolomite whose formation was influenced by the ELIP in the Sichuan Basin of southwestern China. Results show two new pulsed activities at 273.2 ± 9.7 Ma to 269.1 ± 12.0 Ma (ELIP-I) and 263.2 ± 10.3 Ma to 258.7 ± 8.1 Ma (ELIP-II). The two stages of the ELIP magmatism and thermal activity controlled the regional tectonic, sedimentary, and diagenetic evolution and exerted a profound influence on the oil and gas reservoirs, source rocks, and lithofacies paleogeography. This study is the first to interpret the timing of the ELIP from analysis of hydrothermal dolomite and provides new clues and data for improving our understanding of the dynamic formation mechanism and Earth system of the ELIP.

Enrichment Factors and Metallogenic Models of Critical Metals in Late Permian Coal Measures from Yunnan, Guizhou, and Guangxi Provinces

The Late Permian coal measures in eastern Yunnan, western Guizhou, and central Guangxi are significantly enriched in critical metals that could serve as important supplements to conventional critical metal deposits in China. This study collected previous geochronological and geochemical data from the Late Permian coal measures to evaluate the distribution characteristics and enrichment factors of critical metals. Moreover, metallogenic models for critical metals were also developed. The results showed that Late Permian coal measures in Yunnan, Guizhou, and Guangxi provinces exhibited abnormal enrichment in Nb, Zr, and rare earth elements (REY, or REE if Y is excluded). The Emeishan mafic rocks and intermediate-felsic volcanic ash from the Truong Son orogenic belt underwent chemical weathering, with Nb and Zr selectively preserved in situ in the form of heavy minerals (e.g., rutile, zircon, and anatase), which subsequently led to the enrichment of Nb and Zr in bauxite and Al-claystone at the bottom of the Late Permian coal measures. Intermediate-felsic volcanic ash from the Emeishan large igneous province (ELIP) and the Truong Son orogenic belt supplied Nb, Zr, and REY for the middle and upper parts of the Late Permian coal measures. The intermediate-felsic mineral material of the coal measures in the intermediate zone, outer zone, and outside zone of ELIP are derived mainly from the ELIP, the mixture from ELIP and the Truong Son orogenic belt, and the Truong Son orogenic belts, respectively. Nb, Zr, and REY were leached by acidic aqueous solutions and from the parting and roof into underlying coal seams, where they deposited as authigenic minerals or adsorbed ions on organic matter during early coalification.

Southeastward extrusion of the Tibetan Plateau limited by the strong Emeishan large igneous province from earthquake surface wave tomography

Active deformation is ongoing in the southeastern margin of the Tibetan Plateau due to the collision of the Indian and Eurasian continents. While large-scale motion of the surface occurs, the nature of deformation at depth remains unresolved. We construct new lithospheric seismic anisotropic (radially and azimuthally) and shear-wave velocity models using fundamental-mode Rayleigh- and Love-wave phase velocity at periods of 20–100 s obtained from the ChinArray experiment to constrain the deformation style of the crust and upper mantle in the southeastern margin of the Tibetan Plateau. The results show that the uppermost mantle (Moho-90 km) underneath the Tibetan Plateau and northwestern part of the western Yangtze block are characterized with NE-SW oriented azimuthal anisotropy, prominent slow velocity and negative radial anisotropy (VSH < VSV). We interpret that this seismic pattern reflects the southeastward extrusion of the Tibetan uppermost mantle that may thermally erode the northwestern edge and result in the vertically coherent fabric due to the barriers of the left strong Emeishan large igneous province (i.e., south of the western Yangtze block) dominated by the high shear wave velocities. Low velocity anomaly, N-S trending azimuthal anisotropy, and negative radial anisotropy in the uppermost mantle beneath the eastern Yangtze block are most probably associated with vertical migration of hot mantle material from the lithosphere delamination and/or a branch of the Hainan plume.

Mantle Plume‐Lithosphere Interactions Beneath the Emeishan Large Igneous Province

AbstractThe formation of large igneous provinces (LIPs) has been widely believed to be linked to mantle plume activity. However, how the plume modifies the overlying lithosphere, particularly its compositional structure, remains uncertain. Here, we characterize the deep thermochemical structure beneath the Emeishan LIP (ELIP), which is a well‐known Permian plume‐related LIP in China, by taking a multi‐observable probabilistic inversion. Our results find a clear correlation between the lithospheric composition with the ELIP's concentric zones. We infer that the fertile feature of the lithospheric mantle in the ELIP's inner zone was caused by the plume‐derived fertile magmas which infiltrated into and chemically refertilized the ambient depleted lithosphere. This plume‐modified lithospheric compositional structure is likely to be preserved after the plume event, while the present lithospheric thermal structure has been mainly influenced by the subsequent thermal‐tectonic activity. Our results improve our understanding of the physicochemical interactions between the lithosphere and ancient plume.

Mineralogy and Geochemistry of High-Sulfur Coals from the M8 Coal Seam, Shihao Mine, Songzao Coalfield, Chongqing, Southwestern China

Mineral matter, including minerals and non-mineral elements, in coal is of great significance for geological evolution, high-value coal utilization, and environment protection. The minerals and elemental geochemistry of Late Permian coals from the M8 coal seam, Shihao mine, Songzao coalfield in Chongqing, were analyzed to evaluate the sediment source, sedimentary environment, hydrothermal fluids, and utilization prospects of critical metals. The average total sulfur (4.21%) was high in coals, which mainly exists in the forms of pyritic sulfur. Kaolinite, pyrite, calcite, quartz, illite and illite/smectite (I/S) mixed layers, and anatase predominated in coals, with trace amounts of chlorite, ankerite, and siderite. Epigenetic cell- and fracture-filling pyrite, veined calcite, and ankerite were related to hydrothermal fluids and/or pore water after the diagenesis stage. Compared to the world’s hard coals, As and Cd are enriched in the Shihao M8 coals, and Li, Cr, Co, Zr, Mo, Pb, and Tb are slightly enriched. These high contents of sulfophile elements may be related to seawater intrusion. The terrigenous clastics of the Shihao M8 coals originated from the felsic–intermediate rocks atop the Emeishan Large Igneous Provinces (ELIP) (Kangdian Upland), while the roof and floor samples were derived from Emeishan high-Ti basalt. Through the combination of sulfur contents and indicator parameters of Fe2O3 + CaO + MgO/SiO2 + Al2O3, Sr/Ba and Y/Ho, the depositional environment of peat swamp was found to be influenced by seawater. Although the critical elements in coal or coal ash did not reach the cut-off grade for beneficial recovery, the concentration of Li and Zr were high enough in coal ash.

OIB-type mafic–ultramafic rocks in South Guangxi, South China: A record of interaction between Paleo-Tethys subduction and Emeishan large Igneous Province

Late Permian ultramafic–mafic igneous rocks in the Pingxiang area, Guangxi, South China include wehrlite, gabbro, diabase, and amygdaloidal basalt. Geochemical characteristics document interaction between the Emeishan Large Igneous Province (ELIP) and the mantle wedge related to subduction of the Paleo–Tethys. Gabbro and basalt show chondrite–normalized rare earth elements (REEs) and primitive mantle–normalized trace element patterns that parallel ocean island basalts (OIB) and mafic intrusions from the ELIP. Melts in equilibrium with clinopyroxenes, in both wehrlite and gabbro, have REEs and trace element compositions similar to OIB and high–Ti mafic rock of the ELIP. The clinopyroxenes also show a rift–related compositional trend and cover those from the ELIP rocks. These compositional features, along with their moderate initial 87Sr/86Sr and εNd(t) values (−0.8 to +3), are consistent with derivation from an enriched mantle plume source. This is the first time that ultramafic–mafic rocks are reported beyond the established extent of the ELIP and could represent an offshoot from the main mantle plume or indicate that the ELIP plume was considerably bigger than current proposals but has been significantly denuded by subsequent erosion. In addition, the Pingxiang rock units display slightly enriched εNd(t) values and slight negative Nb, Ta, and Zr relative to OIB rocks, indicating an enriched component in the mantle source. Formation of the ELIP spatially and temporally overlapped with subduction of the Paleo–Tethys ocean and interaction between the plume and mantle wedge accounts for the compositional diversity of the ELIP. Such interaction is probably common along the southwestern–southern margin of the Yangtze Block.

Microstructural constraints for the formation of net-textured Fe-Ti oxide ores of the Baima layered intrusion in the Emeishan large igneous province, SW China

The mafic–ultramafic layered intrusions in the Emeishan large igneous province (LIP) host significant amounts of Fe, Ti and V resources. The Fe-Ti oxide ore layers hosted in these layered intrusions are variable in thickness and it is enigmatic how the large amounts of Fe-Ti oxides are accumulated to form the Fe-Ti oxide ore layers. The Fe-Ti oxide ore layers are mainly composed of net-textured ores, however, the processes to form the net-textured ores have not yet been well constrained due to lack of diagnostic microstructural evidence of Fe-Ti oxides in the ores. Here we use the electron back-scattered diffraction (EBSD) technique to characterize the microstructures of Fe-Ti oxides in the net-textured ores of the Baima layered intrusion in the Emeishan LIP, e.g., crystallographic orientation and neighbor-/random-pair misorientation, and to assess the formation model of net-textured ores. The net-textured ores are composed of silicate crystals (olivine, and minor plagioclase and clinopyroxene) isolated by interconnected matrix composed of Fe-Ti oxides (titanomagnetite and ilmenite) and minor sulfides. It is likely that the Fe-Ti oxides simultaneously crystallized from a common Fe–Ti–(P)-rich melt, but postdated olivine and other cumulus minerals. The compaction induced by the gravity of overlying cumulus minerals only caused weak intragrain deformation of Fe-Ti oxides so that the Fe-Ti oxides did not experience intense dynamic recrystallization. Instead, the relatively high temperature and water-rich condition facilitated the operation of static recrystallization, resulting in the straight or smoothly curved grain boundaries of Fe-Ti oxides. The neighbor-pair misorientation patterns of Fe-Ti oxides show the preference for low-angle misorientation, supporting the idea that adjacent crystallized Fe-Ti oxides were rotated to coincident orientation in a melt. This study provides new microstructural evidence for the presence of immiscible Fe-rich melt from which the Fe-Ti oxides crystallized to form the net-textured ores.

Crustal Velocity Structure of the Sichuan–Yunnan Block Revealed by High-Quality Crustal Phase Travel Time

Abstract The Sichuan–Yunnan block is located at the southeastern margin of the Tibetan Plateau, which is the key area as a transition belt from the active plate extrusion zone to the stable Yangtze Craton. Using a semiautomatic measuring method based on a graphical interface, we pick 81,585 precise travel times from 449 local earthquake records and finally obtain a crustal 3D P-wave velocity model of the Sichuan–Yunnan block. The model reveals an unexpected velocity contrast between the shallower and deeper crusts. It is summarized as weakly perturbed low-velocity belts encircling a high-velocity zone in the upper crust and strongly perturbed low-velocity anomalies in the mid-lower crust, respectively. The weak low-velocity anomalies are revealed along the major strike-slip faults, and their small perturbations may imply a slip-driven mechanism. The strong low-velocity anomalies are distributed extensively in the Sichuan–Yunnan block, and their great perturbations may be related to the partial melting of weak material extruded from Tibet. Besides, our result shows noticeable high-velocity anomalies in the core zone of the Emeishan Large Igneous Province (ELIP), which may be an indication of magma solidification from the ancient mantle plume. The result further exhibits an interesting pattern that the strong low-velocity anomalies are partially separated by the high-velocity anomalies in the ELIP. Such a specific pattern probably reflects that the stable zone in the ELIP leads to the bifurcation of weak Tibetan material.

Geological factors for the enrichment of critical elements within the Lopingian (Late Permian) coal-bearing strata in western Guizhou, Southwestern China: Constrained with whole-rock and zircon geochemistry

A number of volcanic ash-bearing layers deposited in the Upper Permian coal-bearing strata on the southwestern margin of the Yangtze Craton are well preserved, and some layers show the enrichment of critical elements such as an assemblage of Zr(Hf)–Nb(Ta)–Ga–REE (REE, rare earth elements). Based on previous work, we studied the source of the Upper Permian volcanic ash-bearing layers widely distributed in western to northwestern Guizhou and the geological factors for the enrichment of critical elements. This article provides a detailed analysis of the mineralogical and geochemical characteristics of the Upper Permian volcanic ash-bearing layers. The mineralogy of the samples is dominated by clay minerals, quartz, anatase, plagioclase, and pyrite, with a few containing K-feldspar, calcite, dolomite, and siderite. The clay minerals are mainly composed of mixed-layer illite/smectite (I/S) and kaolinite. The whole rock geochemistry (Al2O3/TiO2, Nb/Ta vs. Zr/Hf, Nb/Al2O3 vs. Zr/Al2O3, and Th/Al2O3 vs. Zr/Al2O3) and zircon trace elements (Th/Nb vs. Hf/Th, Nb/Yb vs. U/Yb, Ta vs. Nb, and Yb/Sm vs. Y) were used to help determine the source. The results indicate that the sources of the samples include Emeishan high-Ti basalt, intraplate volcanic ash from the Emeishan large igneous province (ELIP), and arc volcanic ash. The critical elements (Zr[Hf]–Nb[Ta]–REE) are mainly derived from the syndepositional intraplate volcanic ash erupted from the ELIP. The results of zircon trace elements and Hf isotope ratios suggest that the magma from the ELIP has gradually evolved from the mantle to the crust, and became more enriched in critical elements such as Nb and Ta. The intraplate volcanic ash from ELIP is the main supplier of critical elements and plays a crucial role in their enrichment through the Late Permian in southwestern China. The paleoenvironment controlled the deposition of volcanic ashes, and most of the critical element enrichment layers developed in weak hydrodynamic environments. The paleogeography and acid rain influenced the migration of critical elements such as Nb, Ta, REE, and Y in some layers. The enrichment of critical elements is also controlled by the regularity and intensity of intraplate volcanic activity.

Molybdenum isotopic fractionation in the Panzhihua mafic layered intrusion in the Emeishan large igneous province, southwest China

Abstract The large Mo isotopic fractionations between different geological reservoirs make this isotopic system a potentially useful tool for constraining the origins of magmatism. However, the effect of magmatic differentiation on Mo isotopes is still controversial. In this study, we obtained Mo isotope data for the Panzhihua gabbroic intrusion (i.e., including mineral separates of clinopyroxene, plagioclase, magnetite, and ilmenite). The whole-rock samples and mineral separates exhibit large Mo isotopic fractionations with δ98/95Mo values as follows: magnetite (–0.73‰ to –0.32‰) &amp;lt; clinopyroxene (–0.32‰ to –0.10‰) &amp;lt; ilmenite (0.06‰ to 0.36‰) &amp;lt; plagioclase (0.33‰ to 0.83‰). Iron-Ti oxides have Mo contents that are one order of magnitude higher than those of clinopyroxene and plagioclase. Mass balance calculations based on Mo isotopes and contents are consistent with an accumulated origin for the Panzhihua intrusion. Rayleigh fractionation modeling shows that the removal of magnetite and ilmenite results in significant Mo isotopic fractionation in the residual magma. Due to the low Mo contents of clinopyroxene and plagioclase, Mo isotopes are not significantly fractionated by the removal of these minerals. Therefore, our study highlights that fractionation of Fe-Ti oxides can cause considerable Mo isotopic fractionation; consequently, caution is needed when using Mo isotopes to infer magma origins.

Trace element systematics of magnetite from alkaline mafic–ultramafic intrusions of the Permian Emeishan large igneous province, SW China

Trace element systematics of magnetite from alkaline mafic–ultramafic intrusions of the Permian Emeishan large igneous province, SW China

Milankovitch cycles recorded by the Late Permian volcanic ash layers in southwestern China

The volcanic activity during the Cenozoic is thought to be forced by Earth's orbit, as it exhibits the Milankovitch cycle. However, the pattern of volcanic activity before the Cenozoic is still unclear. In this study, we studied the volcanic ash-bearing layers preserved in Upper Permian in Southwestern China and analyzed the cycle of volcanic activity from Emeishan Large Igneous Province (ELIP) during the waning stage of Emeishan mantle plume activity. Mineralogy, geochemistry, and gamma-ray (GR) data were used for high-resolution identification of volcanic ash-bearing layers. Al2O3/TiO2, aluminum normalized Th and Sn, and positive anomalies GR data can reflect volcanic ash input. The 206Pb/238U weighted age of zircon ranges from 256.00 ± 2.00 Ma to 251.47 ± 1.29 Ma, indicating synsedimentary volcanic ash. We apply cyclostratigraphic analysis to convert data from the depth domain to the time domain, and then utilize the multitaper method to analyze the cycle of volcanic activity of ELIP. Spectral analysis results reveal that the volcanic activity has long eccentricity (405-kyr), obliquity (∼33-kyr), and precession (∼20-kyr) periods. We propose the astronomical orbital forcing in volcanic activity during the Late Permian, and we have discovered volcanic activity cycles on a larger timescale of astronomical orbital periods (405-kyr long eccentricity). Volcanic activity was significantly correlated with sea level and climate change. During periods of low sea levels, the hot climate causes rapid sea level change, leading to rapid changes in crustal stress and strong volcanic activity. The absolute sea level controls volcanic activity, and the high sea levels suppress volcanic activity.

Mineral Chemistry of Pyrochlore Supergroup Minerals as Records of Nb Mineralization Processes in NYF-Type Pegmatites: A Case Study of the Emeishan Large Igneous Province, SW China

Alkaline igneous rocks have become a potentially important source of Nb, except for the carbonatites. The metallogenetic mechanism of Nb during the magmatic-hydrothermal evolution of alkaline rocks remains ambiguous. From the perspective of Nb minerals, the mineral chemistry of pyrochlore supergroup minerals provides the mineralogical evidence for indicating the respective contributions of magma and hydrothermal fluids to Nb mineralization. In the Miyi County of the Panzhihua-Xichang (Pan-Xi) area, the central zone of the Permian Emeishan large igneous province (ELIP) in SW China, hundreds of Nb-Y-F mineralized pegmatites (NYF-type) are exposed. This study conducted in situ mineral chemistry analyses on four types of pyrochlores to elucidate the Nb mineralization process. Both Pcl-I and Pcl-II exhibit well-developed oscillatory zoning (OZ), representing magmatic pyrochlore formed through disequilibrium crystallization in an oscillatory environment. Pcl-III, with a homogeneous and less variable composition, is also considered of magmatic origin due to its coherent chemical evolution with Pcl-II. Pcl-IV is considered of hydrothermal origin based on its irregular zoning texture, extremely high Na2O contents, and compositional gap compared with magmatic types. The decrease in TiO2 contents, coupled with the increase in Na2O, F, and Nb2O5 contents from Pcl-I to Pcl-III and from the core to the rim of zoned Pcl-II, indicates that fractional crystallization facilitates the crystallization of albite and the enrichment of volatiles, as well as the precipitation of Nb from the early to late stages. During the magmatic-hydrothermal transition stage, the reductive, Na- and F-enriched fluid transports Nb more effectively, leading to further Nb enrichment in pyrochlore. Consequently, there are two-stage Nb mineralization processes associated with the magmatic-hydrothermal evolution in the Miyi pegmatite, with the primary magmatic ore assemblages being the dominant Nb mineralization, which may be a general model for the mineralization of NYF-type pegmatites.

Sedimentology and geochemistry of the Upper Permian transitional shale, Western Guizhou, China: Implications for the environmental effect of the Emeishan large igneous province and organic matter accumulation

The marine-continental transitional shale of the Upper Permian Longtan Formation serves as a crucial target for both shale gas exploration and development, as well as a significant research object of the dramatic geological events during the Middle-Late Permian period. In this study, X-ray diffraction (XRD), polished section, scanning electron microscopy (SEM), energy spectrum analysis (EDS), total organic carbon content (TOC) and elemental geochemistry were conducted to elucidate the sedimentological and geochemical characteristics of the transitional shale in the Longtan Formation and the underlying Emeishan basalt in Western Guizhou. Additionally, the paleoenvironment conditions, the environmental effect of the Emeishan large igneous province and the organic matter enrichment mechanism of the transitional shale are investigated.The sedimentological and geochemical proxies reveal that influenced by seawater and river, the transitional shale of the Longtan Formation in western Guizhou was deposited in a marginal tidal flat-lagoon environment under a warm and humid paleoclimate, anoxic condition, brackish to saline bottom water, high terrigenous detrital input and high sedimentation rate condition. The mineral and elemental composition characteristics show that the transitional shale was predominantly derived from Emeishan basalt, supplemented by contributions from volcanic ash and hydrothermal activity. This suggests that following the eruption of the Emeishan large igneous province in Middle-Late Permian transition, the paleogeographic pattern of high in the west and low in the east was formed in the Upper Yangtze region. The weathering products of the Emeishan basalt were the main source of the Longtan Formation. Intense volcanic activities in the earliest Wuchiapingian potentially induced cooling of the climate, and the elements carried by hydrothermal input likely enhanced paleoproductivity and increased seawater salinity, and was conducive to the suboxic-anoxic water condition.The organic matter contents in transitional shale are extremely high with the highest organic matter content (>20%) of the shale deposited in mire, followed by the shale deposited in tidal flat (10%), whereas the lagoonal shale, predominant in the Longtan Formation, displays the lowest organic matter content (5%). The organic matter enrichment mechanism of transitional shale is primarily attributed to a “preservation model”. The suboxic-anoxic condition and brackish-saline water were conducive to the organic matter preservation. The primary productivity was low and organic matter mainly came from terrestrial higher plants. The warm and humid climate strengthened terrestrial weathering and erosion, consequently increasing terrigenous organic matter input and sedimentation rate. Elevated sedimentation rate reduced the decomposition time of organic matter, thereby also facilitating organic matter preservation. However, the correlations between TOC content and geochemical proxies in lagoonal shale suggest that the warmer and more humid paleoclimate may have increased terrigenous detrital influx and diluted the organic matter content.

Enhanced Denudation of the Emeishan Large Igneous Province and Precipitation Forcing in the Late Permian

AbstractHydroclimate is an important factor controlling landscape evolution. But establishing the impact of hydroclimate is complicated by the influences of other processes and is especially hard to prove for those in deep time from geological record. During the late Permian, voluminous basaltic sediments were derived from the erosion of the Emeishan large igneous province in western South China. They provide a unique record critical in understanding the responses of tropical basaltic erosion to hydroclimate change without impacts of orogenic uplift, lithologic variation, vegetational difference and glacial‐interglacial change. Sampled successions define a negative carbon isotope excursion capable of making regional and global stratigraphic correlations in the middle Wuchiapingian interval corresponding to the final phase of the late Paleozoic ice age. This interval is associated with a petrofacies shift and a decreasing source weathering intensity, a downward shift of erosion loci, and a reduced coastal water paleosalinity. Applying present‐day temperature dependence pattern of basaltic weathering and using land surface temperatures approximated from nearby paleo‐seawaters, denudation rates were calculated for the Emeishan basaltic province and shows an increase from ∼71 to ∼107 m/Ma. This erosional acceleration is temporally correlated with a decrease in paleosalinity and likely linked to enhanced freshwater discharge in the middle Wuchiapingian. Scaling and landscape erosion modeling suggest ∼80%–130% increase in catchment precipitation could have driven this acceleration in denudation. Our work provides a positive test for the hydroclimate forcing on landscape erosion in deep time and underlines the mechanistic linkage of sediments with erosion and climate change.

Coupled volcanic activity and marine anoxia in the Upper Yangtze region prior to the Capitanian mass extinction

The Capitanian mass extinction was a severe biotic crisis in geological history. To present more evidence for this event, this study acquired geochemical data from shelf-margin facies deposits in the Upper Yangtze region, China (i.e., the Shangsi section; the third member of the Maokou Formation [Mao III Member] prior to the Capitanian mass extinction). A significant Hg anomaly is associated with the negative δ13Ccarb excursion in the Mao III Member, suggesting a link to the volcanic activity of the Emeishan large igneous province (ELIP). With increasing water depth, enhanced marine anoxia and stronger water column stratification existed, as evidenced by both organic and inorganic geochemical proxy data. This suggests a possible oceanographic change in response to ELIP volcanism. We propose a three-stage model for the coupled volcanic–climatic–oceanic variations in the Upper Yangtze region during the early Capitanian and the volcanism associated with the ELIP was a potential driving mechanism of the environmental changes and biotic crisis. The ELIP volcanism could have caused the widespread marine anoxia along the continental margin, due to climate warming and the release of nutrient elements. The significant water column stratification and basin restriction were enhanced by climate warming, which would have resulted in expansion of oxygen minimum zones into shelf habitats. This coincided with a decrease in the fusulinacean foraminiferal assemblages and calcareous algae in the Shangsi section. The enhanced marine anoxia and intensified water column stratification may have had a direct role in the death of these organisms. Therefore, widespread marine anoxia/euxinia driven by volcanic activity and climate warming resulted from the ELIP eruption could finally led to the Capitanian biotic crisis.

Spatial distribution of the critical mineral resource element titanium in China and its influencing factors

In China, titanium is found in multi-metal symbiotic ore deposits that present sorting difficulties, low recovery rates, high production costs, and low overall resource utilization rates. The concentration and distribution of titanium in the pedosphere must be better understood to assess the potential titanium resources. The China Geochemical Baseline project obtained harmonized soil and rock geochemical data covering mainland China and provided reliable data for 76 elements (including titanium) from 3382 top (0–25 cm) and 3380 deep (>100 cm) sediment or alluvial soil samples and 12,201 rock samples. In this study, titanium concentrations were determined by X-ray fluorescence spectrometry under strict quality control. The median titanium concentration values in the top and deep samples, which were considered geochemical baseline values, were 3498 mg/kg and 3406 mg/kg, respectively, with mean values of 3661 mg/kg and 3585 mg/kg, respectively. The titanium concentrations ranged from 266 to 24,674 mg/kg and 324 to 25,504 mg/kg in the top and deep soil samples, respectively. The 75 % range (Q25–Q95) of titanium concentrations in the rock ranged from 978 to 8299 mg/kg. The median titanium concentration was 2555 mg/kg in the rock samples, while the mean concentration was 3089 mg/kg. The geochemical map of titanium indicated that low titanium concentrations below Q25 (<3498 and 3406 mg/kg in the top and deep samples, respectively) are primarily distributed in southern Xinjiang, Tibet, Qinghai, Gansu, and Inner Mongolia. The distribution of low titanium content in the soils is likely attributed to these regions being covered by deserts (e.g., Gobi) and glaciers. Soils with high titanium concentrations are widely distributed in the Emeishan large igneous province at the southwest margin of the Yangzi block, which is related to the large distribution of intermediate-basic rock in the area, as well as along the northeast-southwest direction of the Yangtze block, which extends for nearly 1600 km. Moreover, these soils are mainly associated with the black rock system and intermediate-basic dikes. Soil titanium concentrations are affected by various factors, including the occurrence of tectonic activity and distribution of the black rock system, intermediate-basic rock (especially basalt), and VTi magnetite deposits. In particular, the large igneous province area generated by a mantle column represents the main location of VTi magnetite deposit formation and the area with the highest titanium content. In addition to providing detailed information about the titanium distribution in the pedosphere and rock of mainland China, the project can also provide basic geochemical data for the development and utilization of titanium resources and the formulation of critical mineral industry policies.

Water Content and Hydrogen Isotopes of Olivine‐Hosted Melt Inclusions in the Dali Picrites, SW China: Reassessing the Role of Water in the Formation of the Emeishan Large Igneous Province

AbstractThe contribution of water to the formation of large igneous provinces (LIPs) remains controversial. We report the first measurement of water content and hydrogen isotope ratios in olivine‐hosted melt inclusions from the Dali picrites, which belong to the Emeishan LIP (ELIP). The inclusions have a wide range of H2O content (0.01–1.73 wt %) and H isotope ratios (δD = 87 ± 11‰ to −267 ± 14‰). The lowest H isotope ratio is below that of the average mantle but comparable to that of the dehydrated slab. These results suggest that most of the Dali melt inclusions have undergone H+ diffusion and H2O degassing. However, some melt inclusions have higher H2O content and lower δD value, which may have undergone rapid cooling and thereby preserved their magmatic H isotope and water content signatures. The reconstructed H2O content of the primary magma for the Dali picrites is ∼1.35 wt %, much lower than the previous estimate for the ELIP primary magma (3.44 ± 0.89 wt % or 4.0–5.6 wt %). Our results support a moderately hydrous (OIB‐type) magma for the ELIP, instead of a highly hydrous one (arc‐type). The mantle source of the picrites is calculated to contain 0.28–0.52 wt % H2O, and recycled oceanic crust that underwent seawater alteration and subsequent slab dehydration during subduction, causing the low δD value of the melt inclusions. We suggest that the Dali picrites may have formed by partial melting of the recycled oceanic crust and metasomatized mantle peridotite.

Hydrothermal activity and metallogenic environment revealed by seismic wave tomography in Yunnan Province, China

S-wave velocity structures are revealed using double-difference tomography, which shows large-scale low-velocity anomalies around the Xiaojiang and Lijiang−Xiaojinhe fault zones at 10−25 km depth. In contrast, an obvioushigh-speed anomaly exists in the center of Emeishan area, which is consistent with the EmeishanLarge Igneousprovince. Combined with the geological and geophysical data, the low-velocity anomaly might relate to the lower crustal flowof central Tibetan Plateau. The high-velocity anomaly associated with mantle plume in Emeishan would obstruct the crustal flow and limit it around the large deep faults. Meanwhile, the results also show that many mineral resources are mainly concentrated on the major faults and low-velocity zones, indicating that the lower crustal flow and the large deep faults provide conditions for mineral fluids and minerals deposit.